We shall prove the same for 2 cases
1) n is even
2) n is odd
let us 1st prove for n even
case 1 :For n even say 2k (>=2)
3^n + 1 = 3^{2k} + 1 = 9^k + 1 \equiv 2 \pmod 4
so 3^n + 1 is not divisible by 4 so cannot be divisible by 2^n
case 2: for n odd say 2k + 1 ( >=3)
3^n + 1 = 3^{2k+ 1} + 3 = 9^k.3 + 1 \equiv 4 \pmod 8
so so 3^n + 1 is not divisible by 8 so cannot be divisible by 2^n
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